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New EESA Study Indicates Greater Capacity for Carbon Storage in the Subsurface3 min read

by Christina Procopiou on February 6, 2018

Center for Nanoscale Control of Geologic CO2 Discovery Geosciences Program Domain Energy Geosciences Division Energy Resources Program Area Energy Resources Program Domain Fundamental Earth Sciences Program Area Fundamental Geosciences Program GC-Sustainable Earth Geologic Carbon Sequestration Program Resilient Energy Sustainable Energy Systems Program Sustainable Energy Systems Program Domain

 

Jiamin Wan led a team in the study for NCGC.

New research from the Energy Geosciences Division at Berkeley Lab shows that carbon dioxide can penetrate the inner layers of some non-swelling clay minerals which make up the dominant clays in the Earth’s deep subsurface. Results of the work performed at the Center for Nanoscale Controls on Geologic CO2 (NCGC) and the national lab’s Molecular Foundry could help inform practices intended to help limit carbon dioxide emissions, such as carbon capture and storage (CCS) and enhanced oil recovery (EOR).

The study led by EESA staff scientist Jiamin Wan represents ongoing efforts by the NCGC to understand how CO2 behaves one kilometer and farther below the Earth’s surface. A collaboration of seven partner institutions led by Berkeley Lab under the direction of Don DePaolo, NCGC is one of the country’s 32 Energy Frontier Research Centers (EFRCs) funded by the DOE’s Basic Energy Sciences (BES) program.

Previous studies have shown that CO2 can alter typical swelling (or expanding) phyllosilicate minerals such as smectite under the high pressures and temperatures of the deep subsurface. Less is known about the effects of CO2 on non-swelling phyllosilicates illite and muscovite, despite them being the dominant clay minerals in deep subsurface shales and mudstones.

Wan believes there is the assumption that CO2 cannot penetrate layers of minerals that do not expand. “Describing a clay mineral as ‘non-swelling’ means that it does not expand,” says Wan. “Because of this, people don’t imagine that CO2 can get into the mineral’s interlayers. Instead, they imagine CO2 uptake by only the outer surface of the minerals.”

This assumption may lead scientists to underestimate the amount of carbon storage capacity available within the deep subsurface. Wan and her team chose to conduct their experiments on the two similar clay minerals muscovite and illite using muscovite, because of the ability to extract it in large, smooth sheets.

Wan believes there is the assumption that CO2 cannot penetrate layers of minerals that do not expand. “Describing a clay mineral as ‘non-swelling’ means that it does not expand,” says Wan. “Because of this, people don’t imagine that CO2 can get into the mineral’s interlayers. Instead, they imagine CO2 uptake by only the outer surface of the minerals.”

In their study, the researchers subjected single muscovite crystals to incubation with supercritical CO2 (scCO2); then characterized the reacted samples using combined atomic force microscopy (AFM),  X-ray photoelectron spectroscopy, X-ray diffraction, and off-gassing measurements. The first sign that CO2 had penetrated the muscovite sample came when after depressurization the team observed blisters on the muscovite surface (Fig. 1), indicating gas entering the interlayers.

Blistering on the muscovite surface after exposure.

The scientists then confirmed the presence of CO2 using XPS technology, and later quantified the amount of CO2 present by comparing muscovite samples exposed to scCO2 with unexposed control samples to measure the amount of off-gassing of CO2 from the muscovite samples. The exposed samples yielded approximately seven times more CO2 than control samples.

News & Events

EGD Postdoc Fellow Receives Young Researcher Presenter Award1 min read

January 21, 2021

Pramod Bhuvankar, an EGD postdoctoral fellow working with research scientist Abdullah Cihan, received a Young Researcher Presenter Award during the 2020 Computational Methods in Water Resources conference in December. His presentation, “Pore-scale simulations of permeability decline in porous media due to fines migration,” described a pore-scale CFD study of clay mobilization in porous media due…

Berkeley Lab Partners with International Collaborators in Geothermal Energy Research1 min read

January 20, 2021

  Scientists from the Energy Geosciences Division have begun working with European partners on three new geothermal research projects through the Department of Energy’s membership in GEOTHERMICA, a transnational consortium that combines the in-country financial resources and research expertise of 15 participating countries to demonstrate and validate novel concepts in geothermal energy use. This marks the…

EESA Senior Scientist Talks Earthquake Building Resilience1 min read

Berkeley Lab senior scientist David McCallen leads a subproject called Earthquake Sim, or EQSIM, for the DOE’s Energy Exascale Computing Project. He is also professor and director of the Center for Civil Engineering Earthquake Research in the Department of Civil and Environmental Engineering at the University of Nevada, Reno. McCallen recently spoke with Scott Gibson of…

EESA Scientist Coauthors New Comprehensive Guide on Removing CO2 from the Atmosphere2 min read

January 18, 2021

Berkeley Lab researchers are working on ways to sequester more carbon in soil, including through agricultural practices. (Credit: Berkeley Lab) Scientists say that any serious plan to address climate change should include carbon dioxide removal (CDR) technologies and policies, which makes the newly launched CDR Primer an especially vital resource, says Berkeley Lab scientist Margaret Torn, one…

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